Champions Manchester City struggled in this campaign and sit sixth in the table after winning only two of their last 10 league matches.
The victory lifted Brazil to second in South American qualifying with 21 points, four behind leaders Argentina and one ahead of Uruguay in third, both of whom have a game in hand and will clash on Friday.
Both managers have struggled in the Champions League this season, with PSG on seven points and 25th in the standings, one place outside the knockout phase playoff zone, while City are one point ahead in 22nd.
Arsenal displayed their typical end-of-season resilience without even playing that well to win 1-0 at Fulham in the Premier League on Saturday and strengthen their chances of a Champions League spot next season.
Bethany England's early rocket proved enough for Chelsea as they beat newcomers Tottenham Hotspur 1-0.
Arsenal beat Sparta Prague 3-0 in the second leg of their third qualifying round tie to seal a 5-0 aggregate victory and a place in the Champions League proper for the 10th successive season on Wednesday.
Manchester United climbed to third place in their quest for a berth in next season's Champions League.
Images from the Champions League round of 16 second leg matches played on Tuesday
Arsenal restored their five-point lead at the top of the English Premier League with Eddie Nketiah scoring twice in a 3-2 defeat of Manchester United, including a 90th-minute winner.
Real were left with 10 men before halftime when Mbappe saw a straight red after taking down Alaves midfielder Antonio Blanco as the referee overturned his initial decision of booking him with a yellow after consulting with VAR.
After damaging losses to Dinamo Zagreb and Olympiakos Piraeus in their first two fixtures, the Gunners have to win to advance to the knock-out stages
Arsenal dominated the opening period in the Villa Park sunshine.
Arsenal are currently in fourth place and occupy the last Champions League spot with four games remaining.
Arsenal's Eddie Nketiah's two goals enough to beat Oxford United
Wolverhampton Wanderers stunned Tottenham Hotspur 2-1 with stoppage-time goals from Pablo Sarabia and Mario Lemina on Saturday, thwarting the visitors in their bid to reclaim top spot in the Premier League table.
Arsenal kept alive their slim hopes of securing a Champions League spot next season with a 2-1 Premier League victory at Middlesbrough on Monday that left the hosts in deep danger of relegation.
Chelsea, who won the League Cup in February, have 88 points and cannot be caught by 2004 champions Arsenal.
Arsenal will also extend their unbeaten league run to 40 games, two short of Nottingham Forest's record of 42 set over two seasons in 1977-78.
Photos from the UEFA Champions League Round of 16, 2nd leg match played between FC Barcelona and Arsenal at the Camp Nou on Wednesday
Manchester City spent more than 180 million pounds ($223.58 million) -- more than the combined amount paid by the other 19 English top-flight clubs in a relatively quiet window.
Holders Manchester City will take on RB Leipzig, Red Star Belgrade and Young Boys in Group G.
Juventus scored twice in a minute as they came from behind to clinch a dramatic 3-2 win over Olympiakos after Andrea Pirlo had celebrated his 100th Champions League appearance by scoring from a characteristically effortless free kick on Tuesday.
IMAGES from the Premier League matches played on Sunday.
Tottenham have not won any silverware since they beat Chelsea in the 2008 League Cup final.
Confident Arsenal travel to Bayern Munich on Wednesday hoping to tame the German champions for a second time in two weeks, and are promising to attack despite a string of injuries.
Arsenal eased into the group stages of the Champions League on Wednesday by outclassing Celtic 3-1 to enter Thursday's draw where they will be joined by Fiorentina, VfB Stuttgart, Olympiakos and APOEL Nicosia.
Arsenal will have to produce the biggest second leg comeback in a Champions League knockout tie to avoid a seventh successive exit at the last 16 stage when they host Bayern Munich on Tuesday.
Arsenal, VfB Stuttgart and Olympiakos Piraeus all scored 2-0 away wins in their final Champions League playoff matches on Tuesday to take a big stride towards the group stage before next week's second legs.
Arsenal and Barcelona each got a taste of their own medicine on Wednesday but it was the Londoners who recovered from what looked a terminal condition to register a remarkable 2-1 comeback win in the Champions League last-16 first leg.
Chelsea won for the first time in six Premier League matches when they beat relegation-threatened Wolverhampton Wanderers 3-1 at home on Monday.
Images from Sunday's action in the Premier League
Manchester City came from behind to beat Club Brugge 3-1 and secure their place in the Champions League playoffs
Barcelona's Luis Suarez hit a brace and set up a double for a spritely Lionel Messi to score in his first start after injury in a rampant 6-1 Champions League victory over AS Roma on Tuesday.
Images from the English Premier League matches played on Sunday
Arsenal's hopes of qualifying for the Champions League for the 14th time in a row were in the balance after a 1-0 win at home to Udinese in the first leg of the playoffs on Tuesday.
Sunrisers Hyderabad, reeling from three consecutive defeats, will face a resurgent Gujarat Titans in their fifth IPL encounter on Sunday.
Images from the Champions League round of 16 first leg matches played on Wednesday.